1. True or False: London dispersion forces are the only type of
van der Waals forces that occur in nonpolar molecules.
- Answer: False. While London dispersion forces are a type of
van der Waals force and do occur in nonpolar molecules, they are
not the only type; dipole-dipole interactions can also be present if
the nonpolar molecule has an instantaneous dipole.
2. Fill in the blank: The strength of hydrogen bonding is primarily
determined by the __________ of the hydrogen atom to the
electronegative atom it is bonded to.
- Answer: Distance. The closer the hydrogen atom is to the
electronegative atom, the stronger the hydrogen bond.
3. Multiple Choice: Which of the following is not a factor in the
strength of dipole-dipole interactions?
A) Molecular size
B) Molecular shape
C) The presence of a pi bond
D) Electronegativity difference
- Answer: C) The presence of a pi bond. Pi bonds do not
directly affect the strength of dipole-dipole interactions.
4. Open-ended: Explain the role of intermolecular forces in the
boiling point of organic compounds.
- Answer: Intermolecular forces play a crucial role in
determining the boiling points of organic compounds. Stronger
intermolecular forces require more energy to overcome, resulting
in higher boiling points. For example, hydrogen bonds are
stronger than van der Waals forces, so compounds with hydrogen
bonding generally have higher boiling points compared to those
with only van der Waals forces.
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